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Synthesis of Nitrogen‐Doped ZigZag‐Edge Peripheries: Dibenzo‐9a‐azaphenalene as Repeating Unit |
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| Authors: | Reinhard Berger Angelos Giannakopoulos Prince Ravat Dr Manfred Wagner Dr David Beljonne Prof Dr Xinliang Feng Prof Dr Klaus Müllen |
| Affiliation: | 1. Max‐Planck‐Institut für Polymerforschung, Ackermannweg 10, 55128 Mainz (Germany);2. Chimie des Matériaux Nouveaux & Centre d'Innovation et de Recherche en Matériaux Polymères, Université de Mons‐ UMONS/Materia Nova, Place du Parc 20, 7000 Mons (Belgium) |
| Abstract: | A bottom‐up approach toward stable and monodisperse segments of graphenes with a nitrogen‐doped zigzag edge is introduced. Exemplified by the so far unprecedented dibenzo‐9a‐azaphenalene (DBAPhen) as the core unit, a versatile synthetic concept is introduced that leads to nitrogen‐doped zigzag nanographenes and graphene nanoribbons. |
| Keywords: | azomethine ylides graphene nanoribbons organic radicals phenalenes polycyclic aromatic hydrocarbons |
