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Construction of Mesoporous Frameworks with Vanadoborate Clusters |
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| Authors: | Hong Chen Dr Zheng‐Bao Yu Dr Zoltán Bacsik Huishuang Zhao Dr Qingxia Yao Prof Junliang Sun |
| Affiliation: | 1. Berzelii Centre EXSELENT on Porous Materials, Department of Materials and Environmental Chemistry, Stockholm University, 10691 Stockholm (Sweden);2. Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan 430074 (P.R. China);3. College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (P.R. China) |
| Abstract: | A new porous vanadoborate was synthesized by employing the scale chemistry theory with the vanadoborate cluster V10B28. The twofold interpenetrated lvt network was assembled with zinc‐containing elliptical vanadoborate clusters and Zn polyhedra. The single lvt framework contains a three‐dimensional 38×38×20 ring channel system with the pore size (24.7×12.7 Å) reaching the mesoscale, thus indicating the possibility of constructing 3D ordered mesopores with vanadoborate clusters. The porosity of the SUT‐7 structure was confirmed by CO2 adsorption of the as‐synthesized materials. |
| Keywords: | 3D frameworks cluster compounds CO2 adsorption mesoporous materials vanadoborates |
