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投稿时间：2016-01-29 修订日期：2016-02-24
投稿时间：2016-01-29 修订日期：2016-02-24
中文摘要: 研究了Na2EDTA标准滴定溶液测定锡阳极泥中铋的方法。探讨了锡阳极泥的溶样方式、滴定溶液酸度、滴定溶液温度、共存元素干扰、加标回收、方法的准确度与精密度。方法适用于锡阳极泥中5%~20%铋量的测定，尤其是铟量在0.1%及以上时，方法相对标准偏差(RSD)为0.55%~1.4%，加标回收率为99.81%~101.3%。具有操作步骤简单、适用性广、分析结果重现性好与准确度高等优点。
中文关键词: 锡阳极泥 铋 铟 Na2EDTA滴定法
Abstract:A method for the determination of bismuth in tin anode slime using Na2EDTA standard titration solution was studied. Dissolution of tin anode slime, titration acidity, titration temperature, interference of coexisting elements, accuracy and precision of the method were discussed. The method is suitable for the determination of bismuth in tin anode slime with the bismuth concentration of 5%~20% and especially when indium content is more than 0.1%. This method has the advantages of simple operation procedure, wide applicability, good reproducibility and high precision.
文章编号： 中图分类号： 文献标志码：
基金项目:
| Author Name | Affiliation |
| KUAI Lijun | Sub-Institute of Analytical Chemistry, Beijing General Research Institute of Mining and Metallurgy, Beijing 102628,China |
引用文本：
蒯丽君.Na2EDTA滴定法测定锡阳极泥中的铋量[J].中国无机分析化学,2016,6(3):81-86.
KUAI Lijun.Determination of Bismuth in Tin Anode Slime by Na2EDTA Titrimetric Method[J].Chinese Journal of Inorganic Analytical Chemistry,2016,6(3):81-86.
蒯丽君.Na2EDTA滴定法测定锡阳极泥中的铋量[J].中国无机分析化学,2016,6(3):81-86.
KUAI Lijun.Determination of Bismuth in Tin Anode Slime by Na2EDTA Titrimetric Method[J].Chinese Journal of Inorganic Analytical Chemistry,2016,6(3):81-86.
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