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化学进展 2002, Vol. 14 Issue (05): 360- 前一篇   后一篇

• 综述与评论 •

纳米金催化剂上CO低（常）温氧化的研究

王东辉1,2;程代云1;郝郑平2*;史喜成1   

  1. 1. 防化研究院 北京 100083; 2. 中国科学院生态环境研究中心 北京 100085
  • 收稿日期:2001-08-01 修回日期:2002-02-01 出版日期:2002-09-24 发布日期:2002-09-24
  • 通讯作者: 郝郑平
下载PDF ( 3224 ) 引用
导出 被引次数 ( 19 )

Carbon Monoxide Low-temperature Oxidation over Nanosize Gold Catalyst

Wang Donghui1,2;Cheng Daiyun1;Hao Zhengping2*;Shi Xicheng1   

  1. 1. Research Institute of Chemical Defence, Beijing 100083, China; 2. Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China
  • Received:2001-08-01 Revised:2002-02-01 Online:2002-09-24 Published:2002-09-24
  • Contact: Hao Zhengping
金历来被认为是催化惰性的，但近年来有关金催化剂的研究与开发引起人们的兴趣与关注。负载纳米金催化剂显示了良好的催化性能，尤其对一氧化碳氧化反应，能够在低（常）温下将CO氧化为CO2。和其他CO氧化催化剂相比，金催化剂具有高的催化活性、稳定性和抗潮湿的性能，预示着更加广泛的应用前景。本文从制备方法、载体的性质、微粒粒径的大小、预处理、活性机理和催化反应机理等方面进行综合与评述。
关键词： 负载型金催化剂, CO氧化, 制备方法, 载体效应, 纳米微粒
Gold has long been known as being catalytically inactive. However, more interest and attention have been concentrated on the research and development of gold catalysts in recent years. Gold catalysts have been shown good catalytic performances, especially for CO oxidation, and can be used to eliminate CO even below ambient temperature. Compared with other catalysts for CO oxidation, the nanosize gold catalysts have superior catalytic behaviors, such as high catalytic activity, high catalytic stability and high resistance to moisture, and show a continuously increasing and more extensive application prospects. In this review, the preparation factors such as preparation method, support, particle size, pretreatment condition were summarized. The activation and reaction mechanisms were discussed.
Key words: supported gold catalysts, CO oxidation, preparation methods, support effects, nanoparticles

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