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化学进展 2011, Vol. 23 Issue (9): 1985-1992 前一篇   

所属专题： 锂离子电池

• 综述与评论 •

钒系磷酸盐锂离子电池正极材料

任慢慢*, 刘素文, 卢启芳   

  1. 山东轻工业学院 山东省玻璃与功能陶瓷加工与测试技术重点实验室 济南 250353
  • 收稿日期:2010-12-01 修回日期:2011-04-01 出版日期:2011-09-24 发布日期:2011-09-02
  • 通讯作者: 任慢慢 E-mail:rmmtzhx@163.com
  • 基金资助:

    国家自然科学基金项目(No. 50872076),山东省高等学校科技计划项目(J09LD23)和山东大学晶体材料研究所国家重点实验室开放课题项目(KF0905)资助

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导出 被引次数 ( 5 | 1 )

Vanadium-Based Phosphates as Cathode Materials for Lithium Ion Batteries

Ren Manman*, Liu Suwen, Lu Qifang   

  1. Key Laboratory of Processing and Testing Technology of Glass & Functional Ceramic of Shandong Province, Shandong Polytechnic University, Jinan 250353, China
  • Received:2010-12-01 Revised:2011-04-01 Online:2011-09-24 Published:2011-09-02

商业化锂离子电池以锂过渡金属氧化物作正极材料,由于安全性等问题限制了其更广泛的应用。在已经研究和开发的众多新型锂离子电池正极材料中,钒系磷酸盐由于具有较高的对锂电位和理论比容量而成为研究热点。本文综述了各种钒系磷酸盐类锂离子电池正极材料的研究现状,重点对各种材料的结构、制备方法和电化学性能进行了总结,并对改善材料综合性能的方法和机理进行了探讨。

关键词： 钒系磷酸盐, 锂离子电池, 正极材料

Nowadays Li ion batteries have been widely used in many fields as power suppliers for mobile equipment. In commercialized Li ion batteries, cathode materials are mainly lithium transition-metal oxides. However, high cost and security problem limit their large-scale use. Phosphate materials, with a rigid phosphate network and remarkable electrochemical and thermal stability, are considered as a substitution for lithium transition-metal oxides. Among the newly-exploited phosphate cathode materials, vanadium-based phosphates, with stable structure and high theoretical specific capacity, have been attracting much research interest. In this review, recent progress is summarized on the vanadium-based phosphate cathode materials for lithium ion batteries, particularly focusing on the structure, preparation methods, and electrochemical performances of this series of materials. Also, the strategies and the corresponding mechanisms are discussed for the improvement of their general performances.

Contents
1 Introduction
2 Structure characterization and electrochemical perf-ormances of vanadium-based phosphates
2.1 Li3V2(PO4)3
2.2 LiVPO4F
2.3 (Li)VOPO4
2.4 LiVP2O7
3 Preparation methods of vanadium-based phosphates
3.1 High temperature solid state reaction
3.2 Carbothermal reduction
3.3 Sol-gel method
3.4 Microwave solid-state reaction
3.5 Hydrothermal process
3.6 Other methods
4 Strategies for the improvement of general performances
4.1 Coating or doping with high-conductivity materials
4.2 Doping with other ions
5 Conclusions and outlook

Key words: vanadium-based phosphate, lithium-ion batteries, cathode material

中图分类号: 

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[1] Li G H, Azuma H, Tohda M J.Electrochem.Soc., 2002, 149 (6): A743-A747
[2] Takahashi M, Tobishima S, Takei K, Sakurai Y.Solid State Ionics, 2002, 148 (3/4): 283-289
[3] Andersson A S, Thomas J O, Kalska B, Haggstrom L.Elec-trochem.Solid State Lett., 2000, 3 (2): 66-68
[4] Iltchev N, Chen Y, Okada S, Yamaki J.J.Power Sources, 2003, 119/121: 749-754
[5] 吴宇平(Wu Y P),戴晓兵(Dai X B),马军旗(Ma J Q),程预江(Cheng Y J).锂离子电池-应用与实践(Lithium Ion Battery-Application and Practice).北京:化学工业出版社(Beijing:Chemical Industry Press),2004.191-206
[6] Morgan D, Ceder G, Saidi M Y, Barker J.Chem.Mater., 2002, 14(1): 4684-4693
[7] Yin S C, Grondey H, Strobel P, Anne M.J.Am.Chem.Soc., 2003, 125: 10402-10411
[8] Saidi M Y, Barker J, Huang H.Electrochem.Solid-State Soc., 2002, 5 (7): A149-A151
[9] Yin S C, Grondey H, Strobel P, Huang H.J.Am.Chem.Soc., 2003, 125(2): 326-327
[10] Morgan D, Ceder G, Saidi M Y, Barker J, Swoyer J, Huang H, Adamson G.J.Power Sources, 2003, 119/121: 755-759
[11] Saidi M Y, Barker J, Huang H, Swoyer L, Adamson G.J.Power Sources, 2003, 119/121: 266-272
[12] Gaubicher J, Wurm C, Goward G.Chem.Mater., 2000, 12(11): 3240-3242
[13] Barker J, Saidi M Y, Swoyer J L.J.Electrochem.Soc., 2003, 150 (10): 1394-1398
[14] Barker J, Saidi M Y, Swoyer J L.J.Electrochem.Soc., 2004, 151(10): A1670-A1677
[15] Barker J, Gover R K B, Burns P, Bryan P, Saidi M Y, Swoyer J L.J.Electrochem.Soc., 2005, 152 (9): A1776-A1779
[16] Barker J, Gover R K B, Burns P, Bryan P.Electrochem.Solid-State Lett., 2005, 8(6): A285-A287
[17] Barker J, Gover R K B, Burns P, Bryan A, Saidi M Y, Swoyer J L.J.Power Sources, 2005, 146: 516-520
[18] Azmi B M, Ishihara T, Nishiguchi H, Takita Y.Electrochim.Acta, 2002, 48: 165-170
[19] Lim S C, Vaughey J T W, Harrison T A, Dussacka L L, Jacobsona A J, Johnson J W.Solid State Ionics, 1996, 84: 219-226
[20] Dupre N, Wallez G, Gaubicher J, Quarton M.J.Solid State Chem., 2004, 177: 2896-2902
[21] Dupre N, Gaubicher J, Mercier T L, Wallez G, Angenault J, Quarton M.Solid State Ionics, 2001, 140: 209-221
[22] Song Y, Peter Y Z, Whittingham S.J.Electrochem.Soc., 2005, 152(4): A721-A728
[23] Ayyappana P, Ramanana A, Joyb P A.Solid State Ionics, 1998, 107: 53-57
[24] Amoros P, Marcos M D, Roca M, Alamo J, Beltrán-Porter A, Beltrán-Porter D.J.Phy.Chem.Solids, 2001, 62: 1393-1399
[25] Kerr T A, Gaubicher J, Nazarz L F.Electrochem.Solid-State Lett., 2000, 3 (10): 460-462
[26] Gaubicher J, Mercier T L, Chabre Y, Angenault J, Quarton M.J.Electrochem.Soc., 1999, 146 (12): 4375-4379
[27] Azmia B M, Ishihara T, Nishiguchi H, Takita Y.J.Power Sources, 2005, 146: 525-528
[28] Bustam M A, Hasanaly S M, Ishihara T, Takita Y.Ionics, 2005, 11: 402-405
[29] Barker J, Saidi M Y, Swoyer J L.J.Electrochem.Soc., 2004, 151(6): A796-A800
[30] Wurm C, Morcrette M, Rousse G, Dupont L, Masquelier C.Chem.Mater., 2002,14 (6): 2701-2710
[31] Barker J, Gover R K B, Burns P, Bryan A.Electrochem.Solid-State Lett., 2005, 9: A446-A4448
[32] Patoux S, Wurm C, Morcrette M, Rousse G, Masquelier C.J.Power Sources, 2003, 119/121: 278-284
[33] Barker J, Saidi M Y, Swoyer J L.J.Electrochem.Soc., 2003,150 (6): A684-A688
[34] Huang H, Yin S C, Kerr T, Taylor N, Nazar L F.Adv.Mater., 2002, 14(21): 1525-1528
[35] Li Y Z, Zhou Z, Gao X P, Yan J.Electrochim.Acta, 2007, 52: 4922-4926
[36] Ren M M, Zhou Z, Gao X P, Peng W X, Wei J P.J.Phys.Chem.C, 2008, 112: 5689-5693
[37] Li Y Z, Zhou Z, Gao X P, Yan J.J.Power Sources, 2006, 160: 633-637
[38] Ren M M, Zhou Z, Su L W, Gao X P.J.Power Sources, 2009, 189: 786-789
[39] Yang G, Ji H M, Liu H D, Qian B, Jiang X F.Electrochim.Acta, 2010, 55: 3669-3680
[40] Yang G, Liu H D, Ji H M, Chen Z Z, Jiang X F.Electro-chimi.Acta, 2010, 55: 2951-2957
[41] 任慢慢(Ren M M),李宇展(Li Y Z),周震(Zhou Z),高学平(Gao X P),阎杰(Yan J).电池(Battery bimonthly), 2006, 36:13-14
[42] Ren M M, Zhou Z, Gao X P, Liu L, Peng W X.J.Phys.Chem.C, 2008, 112: 13043-13046
[43] Chang C X, Xiang J F, Shi X X, Han X Y, Yuan L J, Sun J T.Electrochim.Acta, 2008, 54: 623-627
[44] Burba C M, Frnch R.Solid State Ionics, 2007, 177: 3445-3454
[45] Yu F, Zhang J J, Yang Y F, Song G Z.J.Solid State Electro-chem., 2010, 14:883-888
[46] Tarascon J M, Armand M.Nature, 2001, 414: 359-367
[47] Nanjundaswamy K S, Padhi A K, Goodenough J B, Okada S, Ohtsuka H, Arai H, Yamaki J.Solid State Ionics, 1996, 92 (1/2): 1-10
[48] 施志聪(Shi Z C),杨勇(Yang Y).化学进展(Progress in Chemistry), 2005, 4: 604-613
[49] Sun Y K, Myung S T, Kim M H.J.Am.Chem.Soc., 2005, 127:13411-13419
[50] Wang Y G, Wang Y R, Hosono E, Wang K X, Zhou H S.Angew.Chem.Int.Ed., 2008, 47: 7461-7465
[51] Reddy M V, Subba Rao G V, Chowdari B V R.J.Power Sources, 2010, 195: 5768-5774
[52] Wang F, Wu F, Wu C, Bai Y, Wang L.Adv.Mater.Research Vols., 2010, 129/131: 521-525
[53] Wang L, Zhang L C, Lieberwirth I, Xu H W, Chen C H.Electrochem.Comm., 2010, 12: 52-55
[54] Jiang T, Du F, Zhang K J, Wei Y J, Li Z, Wang C Z, Chen G.Solid State Sciences, 2010, 12: 1672-1676
[55] Tang A P, Wang X Y, Liu Z M.Materials Lett., 2008, 62: 1646-1648
[56] Wang L J, Zhou X C, Guo Y L.J.Power Sources, 2010, 195: 2844-2850
[57] Rui X H, Li C, Chen C H.Electrochim.Acta, 2009, 54: 3374-3380
[58] Chang C X, Xiang J F, Shi X X, Han X Y, Yuan L J, Sun J T.Electrochim.Acta, 2008, 53: 2232-2237
[59] Wang X Y, Yin S Y, Zhang K L, Zhang Y X.J.Alloy Comp., 2009, 486: L5-L7
[60] Wang J W, Liu J, Yang G L, Zhang X F, Yan X D, Pan X M, Wang R S.Electrochim.Acta, 2009, 54: 6451-6454
[61] Jiang T, Pan W C, Wang J, Bie X F, Du F, Wei Y J, Wang C Z, Chen G.Electrochim.Acta, 2010, 55: 3864-3869
[62] Jiang T, Wei Y J, Pan W C, Li Z, Ming X, Chen G, Wang C Z.J.Alloys Comp., 2009, 488: L26-L29
[63] Zhang L, Wang X L, Xiang J Y, Zhou Y, Shi S J, Tu J P.J.Power Sources, 2010, 195: 5057-5061
[64] Ren M M, Zhou Z, Li Y Z, Gao X P, Yan J.J.Power Sources, 2006, 162: 1357-1362
[65] Chen Y H, Zhao Y M, An X N, Liu J M, Dong Y Z, Chen L.Electrochim.Acta, 2009, 54: 5844-5850
[66] Kuang Q, Zhao Y M, An X N, Liu J M, Dong Y Z, Chen L.Electrochim.Acta, 2010, 55: 1575-1581
[67] Huang J S, Yang L, Liu K Y, Tang Y F.J.Power Sources, 2010, 195: 5013-5018
[68] Dai C S, Chen Z Y, Jin H Z, Hu X G.J.Power Sources, 2010, 195: 5775-5779
[69] Barker J, Gover R K B, Burns P, Bryan A.J.Electrochem.Soc., 2007, 154 (4): A307-A313
[70] 刘素琴(Liu S Q), 李世彩(Li S C), 黄可龙(Huang K L),陈朝晖(Chen Z H).物理化学学报(Acta Phys.-Chim.Sin.), 2007, 23: 537-542
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摘要

钒系磷酸盐锂离子电池正极材料