化学学报 ›› 2002, Vol. 60 ›› Issue (3): 408-412. 上一篇    下一篇

研究论文

相转移方法制备银纳米粒子单层膜

李德刚;陈慎豪;赵世勇;王春涛   

  1. 山东大学化学系,济南(250100)
  • 发布日期:2002-03-15

Production of the Monolayer of Ag Nanoparticles by Phase Transferring

Li Degang;Chen Shenhao;Zhao Shiyong;Wang Chuntao   

  1. Department of Chemistry, Shandong University,Jinan(250100)
  • Published:2002-03-15

在油酸钠保护下用NaBH_4还原AgNO_3,制得了银纳料粒子胶体溶液。利用相转 移剂NaH_2PO_4等,使Ag纳料粒子在水/朋机相界面之间形成薄膜。形成的Ag纳料 粒子膜可以转移到玻璃等基质上,讨论了其转移机理;并用石英晶体微天平(QCM )宣检测了银纳料粒子的相转移量。

关键词: 银, 纳米相材料, 胶体, 相转移反应

Ag nanoparticles were produced by the reduction of AgNO_3 with the protecting of sodium oleate using NaBH_4. After adding the transferring regent NaH_2PO_4, a film of Ag nanoparticles was formed at the interface of water/organic phase. The film could be transferred to a substrate such as glass. The mechanism of the transfer of the film was discussed. Quartz Crystal Microbalance (QCM) was also used to measure the transferred colloidal quantity for Ag nanoparticles.

Key words: SILVER, NANOPHASE MATERIALS, COLLOID, PHASE TRANSFER REACTION

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