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化学学报
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化学学报 ›› 2001, Vol. 59 ›› Issue (1): 1-5.    下一篇

研究论文

光散射法研究丙烯酸十八酯和苯乙烯微乳液 共聚机理

朱卫忠;李干佐;郑立强;刘少杰;水玲玲;梁好均;吴奇   

  1. 山东大学教育部胶体与界面化学重点实验室;中国科学技术大学化学院
  • 发布日期:2001-01-15

Particle nucleation during the microemulsion co-polymerization of acrylic octadecyl ester and styrene by laser light scattering method

Zhu Weizhong;Li Ganzuo;Zheng Liqiang;Liu Shaojie;Shui Lingling;Liang Haojun;Wu Qi   

  • Published:2001-01-15

PDF

480

被引次数

36 | 3

在十六烷基溴化吡啶/叔丁醇/15%丙烯酸十八酯和苯乙烯/水体系的O/W微乳液中，使用动态光散射法，研究其中两种单体共聚反应的成核机理。结果表明，聚合过程中乳胶粒成核位置主要在增溶胶囊的单体微珠中，乳胶粒主要依靠单体微珠不断提供单体而长大。

关键词: 丙烯酸酯, 苯乙烯, 乳液聚合, 胶束, 光散射, 聚合

The phase behavior of the system of cetylpyridine bromide/t- butanol/15% (acrylic octadecyl ester and styrene)/water was measure at 25.4℃. The kinetic of the acrylic octadecyl ester and styrene co- polymerization in O/W microemulsion system for cetyl pyridine bromide/t-butanol-15% [acrylic octadecyl ester and styrene (1:2.5)] /water was studied by LLS method. The mechanism of nucleation of latex particles is discussed. The most possible nucleation locations of the acrylic octadecyl ester and styrene latex particles are solulization micelles and monomer microdrops.

Key words: PROPENOIC ACID ESTER, STYRENE, EMULSION POLYMERIZATION, MICELLE, LIGHT SCATTERING, POLYMERIZATION

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