应用化学 ›› 1991, Vol. 0 ›› Issue (5): 28-31.

• 研究论文 • 上一篇    下一篇

聚4-氨基联苯溶液的性质

石玉军, 穆绍林   

  1. 扬州师范学院化学系, 扬州 225002
  • 收稿日期:1990-04-07 修回日期:1990-10-05 出版日期:1991-10-10 发布日期:1991-10-10

SOLUTION PROPERTY OF POLY(4-AMINOBIPHENYL)

Shi Yujun, Mu Shaolin   

  1. Department of Chemistry, Yangzhou Teacher's College, Jiangsu, Yangzhou 225002
  • Received:1990-04-07 Revised:1990-10-05 Published:1991-10-10 Online:1991-10-10

摘要: 本文报导了聚4-氨基联苯的电化学合成,测定了它的ESR、IR及紫外可见光谱。聚合物在THF、DMF和DMSO中能全部溶解。界面移动法测得聚4-氨基联苯的DMF饱和溶液中正离子的迁移率为1.48×10-8m2·S-1·V-1

关键词: 聚4-氨基联苯, 溶液电导率, 离子迁移率

Abstract: Poly (4-aminobiphenyl) was prepared by electrochemical method and its ESR、IR anduv-visible spectra have been studied.The poly (4-aminobiphenyl) completely dissolves in THF, DMF and DMSO.The mobility of the positive ion of poly (4-aminobiphenyl) in itssaturated solution of DMF was determined by the moving boundary method to be 1.48×10-8m2·s-1·V-1.

Key words: poly(4-aminobiphenyl), solution conductivity, ion mobility