| 新型含葡萄糖基手性Salen配体及其Mn3+、Fe3+、Co2+、Cu3+配合物的合成与表征 |
| Synthesis and Characterization of a Novel Chiral Salen Ligand with a Glucose Moiety and Its Mn(Ⅲ), Fe(Ⅲ), Co(Ⅱ) and Cu(Ⅱ) Complexes |
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| 摘要: |
| 关键词: 葡萄糖衍生物 手性金属配合物 Salen配体 Schiff碱 环己二胺 |
| 基金项目: |
| Abstract: A novel chiral Salen ligand with a glucose moiety was synthesized from the condensation of 1,2:5,6-di-O-isopropylidene-3-O-methylene-[5-(3-tert-butyl-2-hydroxy benzaldehyde)]-α-D-glucofuranose with (1R,2R)-1,2-diaminocyclohexane. Several chiral complexes of Mn3+, Fe3+, Co2+ and Cu2+ were prepared from this ligand. Both the ligand and the complexes were characterized by elemental analysis, NMR, IR, MS, and UV-Vis. |
| Keywords: glucose derivative chiral metal complex Salen ligand Schiff base diaminocyclohexane |
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| 赵姗姗,赵继全,赵东敏.新型含葡萄糖基手性Salen配体及其Mn3+、Fe3+、Co2+、Cu3+配合物的合成与表征[J].无机化学学报,2006,22(6):1133-1136. |
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