| 水杨醛缩L-天冬氨酸过渡金属配合物的合成及表征 | |||||||||
| SYNTHESIS AND CHARACTERIZATION OF TRANSITION METAL COMPLEXES WITH A SCHIFF BASE LIGAND DERIVED FROM SALICYLIDENE AND ASPARTIC ACID | |||||||||
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| 摘要: 合成了新的水杨醛天冬氨酸席夫碱配体及其铜、锌、钴、镍配合物，并利用元素分析、摩尔电导、热分析、红外光谱、电子光谱及顺磁共振等手段进行表征，确定配合物的化学组成为K［ML］·nH2O，式中L=C11H7NO, M=Cu2+、Zn2+、Co2+、Ni2+，相应地n=2、2、3、7/2。 | |||||||||
| 关键词: 氨基酸席夫碱 过渡金属配合物 合成 | |||||||||
| 基金项目: | |||||||||
| Abstract: A few Schiff base complexes: K［ML］·nH2O, where H2L=L-aspartic-salicylidene Schiff base, M=Cu2+, Zn2+, Co2+, Ni2+, n=2,2,3,7/2, have been synthesized. The new compounds were characterized by elemental analyses, molar conductances, infrared spectra, electronic spectra, thermal analyses and ESR spectra. | |||||||||
| Keywords: L-aspartic acid Schiff base transition metal complex synthesis | |||||||||
| 摘要点击次数: 1274 | |||||||||
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| 史卫良,陈德余,吴清洲.水杨醛缩L-天冬氨酸过渡金属配合物的合成及表征[J].无机化学学报,1999,15(6):761-765. | |||||||||
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