| 锗(Ⅳ)与邻苯二酚和含氮配体混配配合物的合成与表征 |
| SYNTHESIS AND CHARACTERIZATION OF MIXED LIGAND COMPLEXES OF GERMANIUM(Ⅳ) WITH CATECHOL AND N-LIGAND |
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| 摘要: 首次合成了四种锗(Ⅳ)与邻苯二酚和α-氨基酸的混配配合物［Ge(C6H4O2)2·2AA］,(AA=α-甘氨酸(gly)、α-苏氨酸(thre)、α-缬氨酸(val)、α-白氨酸(leu)；两种锗(Ⅳ)与邻苯二酚和杂环二胺类的混配配合物［Ge(C6H4O2)2·(DA)］，(DA=2,2′-联吡啶(bipy)、1，10-邻菲咯啉(phen)。用元素分析、摩尔电导、红外和紫外光谱、核磁及热分析等方法研究了配合物的组成和性质，表明配合物有两种结构类型，一类是反式八面体，另一类为顺式畸变八面体。 |
| 关键词: 锗 邻苯二酚 α-氨基酸 杂环二胺 混配配合物 合成 |
| 基金项目: |
| Abstract: Four new mixed ligand complexes of germanium (Ⅳ) with catechol and α-aminoacid (AA=glycine, threonine, valine and leucine), and two new mixed ligand complexes of germanium (Ⅳ) with catechol and hybrid ring diamine (DA=2,2′-bipyridine and 1,10-phenanthroline) were synthesized and characterized by elemental analyses, infrared and electronic spectra, molar conductance, 1H NMR and thermal analyses. The compositions of the copmlexes were confirmed to be ［Ge(C6H4O2)2·2AA］ and ［Ge(C6H4O2)2·(DA)］. Some properties of the complexes were studies. |
| Keywords: germanium (Ⅳ) catechol α-aminoacid hybrid-ringdiamine mixed ligand complex synthesis |
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| 陈静,李五聚,杨林,史(?),娄全龄.锗(Ⅳ)与邻苯二酚和含氮配体混配配合物的合成与表征[J].无机化学学报,1998,14(3):261-265. |
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