| 新型席夫碱配体及其Mn3+、Fe3+、Ni2+、Cu2+配合物的合成与表征 |
| Synthesis and Characterization of Complexes of Mn(Ⅲ), Fe(Ⅲ), Ni(Ⅱ) and Cu(Ⅱ) with a New Schiff Base Ligand |
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| 摘要: |
| 关键词: 5-叔丁基-3-甲酰基-4-羟基苯甲酸 (1R，2R)-N，N′-双(5-叔丁基-3-甲酰基-4-羟基苯甲酸甲酯)缩环己二胺 手性金属配合物 |
| 基金项目: |
| Abstract: Chial Complexes of Mn3+, Fe3+, Ni2+ and Cu2+ were prepared from chiral Schiff Base ligand obtained by condensation of new type methyl 5-(1,1-dimethylethyl)-3-formyl-4-hydroxybenzoate synthesized by this work with (1R, 2R)-1,2-diaminocyclohexane. The new chiral ligand and complexes were characterized by elementary analysis, 1H NMR, IR and UV-Vis. |
| Keywords: 5-(1,1-dimethylethyl)-3-formyl-4-hydroxybenzoic acid (1R, 2R)-N, N′-bis(methyl 5-(1,1-dimethylethyl)-3-formyl-4-hydroxybenzoate)-1,2-diaminocyclohexane chiral metal complex |
| 投稿时间：2005-04-28 修订日期：2005-06-22 |
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| 张雅然,赵继全,何乐芹,张松梅.新型席夫碱配体及其Mn3+、Fe3+、Ni2+、Cu2+配合物的合成与表征[J].无机化学学报,2005,21(12):1871-1874. |
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