Lasiodonin Acetonide的NMR数据解析

摘要/Abstract

摘要：

对lasiodonin acetonide进行了¹H和¹³C NMR检测，参考lasiodonin, maoecrystal T, wikstroemioidin B和rabdocoetsin A的¹H、¹³C NMR数据，通过DEPT和¹H-¹H COSY、HSQC、HMBC等2D NMR技术对该化合物所有的¹H和¹³C NMR信号进行了全归属和详细解析.

关键词: NMR, 归属, 2D NMR, lasiodonin acetonide

Abstract:

A new diterpene，lasiodonin acetonide，was isolated from Chinese medicinal herb Rabdosia rubescens (Hems L.). Referring to the ¹H and ¹³C NMR spectra of lasiodonin，maoecrystal T，wikstroemioidin B and rabdocoetsin A，its structure was determined to be 1α，6β，7β，11β-tetrahydroxy-cyclic，1，11-(1-methyl- ethylidene acetal)-7，20-epoxy- Kaur-16-en-15-one by 1D (¹H，¹³C NMR and DEPT) and 2D (¹H-¹H COSY，HMQC and HMBC) NMR techniques.

Key words: NMR, assignments, 2D NMR, lasiodonin acetonide

中图分类号:

O641

张海艳, 赵天增, 郭唯, 吴鸣建. Lasiodonin Acetonide的NMR数据解析[J]. 波谱学杂志, 2005, 22(2): 155-162.

ZHANG Hai-Yan, ZHAO Tian-Zeng, GUO Wei, WU Ming-Jian. An NMR Study of Lasiodonin Acetonide[J]. Chinese Journal of Magnetic Resonance, 2005, 22(2): 155-162.

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